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相关概念视频

Batteries and Fuel Cells03:12

Batteries and Fuel Cells

A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
Nitriles to Amines: LiAlH4 Reduction00:55

Nitriles to Amines: LiAlH4 Reduction

Nitriles are reduced to amines in the presence of strong reducing agents like lithium aluminum hydride through a typical nucleophilic acyl substitution. The reaction requires two equivalents of the reducing agent. The reducing agent acts as a source of hydride ions.
As shown below, the mechanism involves three steps. Firstly, the hydride ion acting as a nucleophile attacks the nitrile carbon to form an anion. In the second step, a second equivalent of the hydride ion attacks the anion to...
Electrophilic Aromatic Substitution: Nitration of Benzene01:20

Electrophilic Aromatic Substitution: Nitration of Benzene

The nitration of benzene is an example of an electrophilic aromatic substitution reaction. It involves the formation of a very powerful electrophile, the nitronium ion, which is linear in shape. The reaction occurs through the interaction of two strong acids, sulfuric and nitric acid.
Voltaic/Galvanic Cells02:47

Voltaic/Galvanic Cells

Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Preparation and Reactions of Sulfides02:26

Preparation and Reactions of Sulfides

Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.

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相关实验视频

Updated: May 16, 2026

Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
10:03

Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques

Published on: November 11, 2013

-硫电池阴极由-烯酸相互作用激活.

Juchen Guo1, Zichao Yang, Yingchao Yu

  • 1School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, New York 14853, USA. jguo@engr.ucr.edu

Journal of the American Chemical Society
|December 14, 2012
PubMed
概括

研究人员开发了一种新的硫化-碳复合物,用于高能电池. 这种材料有效地防止了聚硫化物穿,从而使离子电池具有高容量和高效率.

科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 储能 储能 储能 储能 储能 储能

背景情况:

  • 硫化 (Li2S) 是用于高能离子电池的有前途的阴极材料.
  • 防止聚硫化物溶解和穿对于Li2S阴极稳定性至关重要.
  • 现有的方法通常需要金属阳极,这引发了安全问题.

研究的目的:

  • 开发一种新的硫化-碳复合材料的正极材料.
  • 创建一个固有的机制,在阴极结构内隔离多硫化物.
  • 为了评估离子电池中新复合物的电化学性能.

主要方法:

  • 合成硫化-碳复合物,通过分散Li2S在由聚合物前体 (聚烯二) 衍生的碳宿主中.
  • 利用聚合物前体中的离子和基之间的相互作用来控制Li2S分布.
  • 碳化前体形成Li2S-碳复合结构.
  • 评估复合材料作为半电池电池设置中的阴极材料.

主要成果:

  • 合成的Li2S-碳复合材料显示了Li2S的均分散.
  • 复合建筑有效地隔离了多硫化物,减轻了穿.
  • 阴极材料表现出高电荷/放电容量.

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相关实验视频

Last Updated: May 16, 2026

Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
10:03

Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques

Published on: November 11, 2013

In Situ Neutron Powder Diffraction Using Custom-made Lithium-ion Batteries
11:25

In Situ Neutron Powder Diffraction Using Custom-made Lithium-ion Batteries

Published on: November 10, 2014

Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy
07:20

Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy

Published on: January 20, 2023

  • 在电化学循环过程中实现了优异的库伦比克效率.
  • 结论:

    • 拟议的复合结构在均分配Li2S和隔离聚硫化物方面是有效的.
    • 这种方法为开发用于先进离子电池的稳定和高性能硫化阴极提供了可行的途径.
    • 该方法避免了对金属阳极的需求,提高了电池的安全性和能量密度.