在 perfluorosulfonic 酸质子导电膜中的结构和放松之间的相互作用
Guinevere A Giffin1, Gregory M Haugen, Steven J Hamrock
1Department of Chemical Sciences, University of Padova, Via Marzolo 1, I-35131 Padova, Italy.
Journal of the American Chemical Society
|December 20, 2012
概括
这项研究揭示了受相当重量 (EW) 影响的离子体膜结构如何影响性质. 较高的EW膜显示出增加的质子交换限制,影响导电性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 聚合物科学 聚合物科学
背景情况:
- 离子体膜对于燃料电池的性能至关重要.
- 了解结构属性关系是优化膜设计的关键.
研究的目的:
- 为了研究3M离子体膜的结构变化,具有不同的等重量 (EW).
- 为了将这些结构变化与膜性质,特别是导电性相关联.
主要方法:
- 广角X射线衍射 (WAXD) 来分析膜结构.
- 振动光谱学用于研究化学变化和水相互作用.
- 在高温下进行导电性测量以评估性能.
主要成果:
- 在膜中观察到有序的疏水区域 (除了700 EW).
- 质子解离和聚四乙烯域结晶性变化与EW和水含量相关.
- 导电性遵循Vogel-Tammann-Fulcher (VTF) 行为,表明质子通过移位体 (DB) 迁移.
- 较小的EW膜显示出更大的界面导电性贡献;较大的EW膜更多地依赖DB质子交换.
结论:
- 膜结构显著影响质子导电性.
- 在较高的EW中,DB之间的质子交换变得限制速度.
- 优化离子体膜结构对于高效的燃料电池运行至关重要.
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