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Updated: May 14, 2026

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
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在非导体基板上经过电化学介导的原子转移激素聚合:通过催化剂扩散控制的刷子生长

Bin Li1, Bo Yu, Wilhelm T S Huck

  • 1State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 China.

Journal of the American Chemical Society
|January 25, 2013
PubMed
概括

表面启动的原子转移基聚合 (SI-ATRP) 使用Cu(I) / L激活器梯度来控制聚合物生长. 通过控制可调节的聚合物动力学间隙距离和基板角度来移植聚合物刷.

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Radical Chain-Growth Polymerization: Mechanism

The radical chain-growth polymerization mechanism consists of three steps: initiation, propagation, and termination of polymerization. The polymerization initiates when a free radical generated from the radical initiator adds to the unsaturated bond in the monomer. The unpaired electron of the free radical and one π electron in the unsaturated bond creates a σ bond between the free radical and the monomer. As a result, the other π electron in the unsaturated bond converts this species into the...
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