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一个新合成的酸二胺衍生物的驼式行为

Jiaxiang Chu1, Christos E Kefalidis, Laurent Maron

  • 1State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Road, Shanghai 200032, People's Republic of China.

Journal of the American Chemical Society
|May 11, 2013
PubMed
概括

研究人员合成了一种新型的替代的尼特利胺,这是一个具有多功能反应性的稳定化合物. 这种有机金属复合物与各种不和分子发生反应,展示了其在化学合成中的潜力.

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Diazonium Group Substitution with Halogens and Cyanide: Sandmeyer and Schiemann Reactions01:20

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Arenediazonium substitution reactions occur when the diazonium group is substituted by various functional groups such as halides, hydroxyl, nitrile, etc. For instance, arenediazonium salts react with copper(I) salts of chloride, bromide, or cyanide to form corresponding aryl chlorides, bromides, and nitriles. These reactions are named Sandmeyer reactions. Although the mechanism of this reaction is complicated, as illustrated in Figure 1, they are believed to progress via an aryl copper...