在AlFe2B2中的磁热效应:来自地球上丰富的元素的磁性制冷剂
Xiaoyan Tan1, Ping Chai, Corey M Thompson
1Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, Tallahassee, Florida 32306, United States.
Journal of the American Chemical Society
|June 5, 2013
概括
研究人员开发了AlFe2B2,一种轻质磁性材料. 它在室温附近显示出显著的磁热效应 (MCE),使其成为稀土元素的有希望的替代品.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 固态化学 固态化学
背景情况:
- 寻找高效的磁热材料对于开发先进的冷却技术至关重要.
- 多层金属化物为新的磁性特性和应用提供了潜在的潜力.
- 稀土元素,通常用于磁热材料,面临供应和成本挑战.
研究的目的:
- 为了合成和描述AlFe2B2化合物.
- 为了研究AlFe2B2.2.的磁性和磁热性质.
- 评估AlFe2B2作为一种没有稀土的磁热材料的潜力.
主要方法:
- 通过弧和Ga流量方法进行合成.
- 层层的晶体结构的结构分析.
- 磁性测量以确定铁磁性和订制温度.
- 磁热效应 (MCE) 测量作为磁场的函数.
主要成果:
- Fe2B2成功合成,揭示了具有交替Al和[Fe2B2]层的分层结构.
- 该化合物表现出漫游铁磁性,其基里温度为307K.
- 观察到显著的磁热效应:在2T时有4.1Jkg{-1}K{-1}和在5T时有7.7Jkg{-1}K{-1}.
- 这些MCE值是金属化物和室温附近的122家族材料报告的最高值.
结论:
- AlFe2B2是一种有前途的无稀土磁热材料.
- 它的轻量化性质和大量使用地球元素使其对环境无害且具有成本效益.
- 在室温附近的大量MCE突出了其在磁性制冷应用中的潜力.
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