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Updated: May 9, 2026

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
10:01

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase

Published on: December 4, 2017

在 O2 耐受性膜结合 [NiFe] 酶中的 [4Fe-3S] 邻近集群的氧依赖性结构转化:DFT 研究

Vladimir Pelmenschikov1, Martin Kaupp

  • 1Technische Universität Berlin, Institut für Chemie, Theoretische Chemie, Sekr. C7, Strasse des 17. Juni 135, 10623 Berlin, Germany. pelmentschikov@mailbox.tu-berlin.de

Journal of the American Chemical Society
|July 16, 2013
PubMed
概括

破碎对称密度函数理论揭示了膜结合的[NiFe]-酶中的近端 [4Fe-3S]集群在氧化还原反应期间如何改变结构. 一个关键的 conformational 切换和质子转移发生在超氧化状态,低激活能量.

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