开发大带间隙结合合聚合物,用于高效的正规单体和体有机太阳能电池
1Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, Sichuan University , 29 Wangjiang Road, Chengdu 610064, China.
Journal of the American Chemical Society
|August 22, 2013
概括
新的合共聚合物PBDTFBZO和PBDTFBZS提高了聚合物太阳能电池的效率. 这些材料提供了更好的电压,电流和充电因子,从而使单一和联设备的功率转换效率更高.
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 太阳能光伏发电是如何实现的
背景情况:
- 结合型共聚合物对于有机太阳能电池至关重要.
- 调整聚合物骨干结构会影响电子特性和设备性能.
- 和硫的结合可以提高电荷运输和能量水平.
研究的目的:
- 为了合成和描述新型联共聚物 (PBDTFBZO和PBDTFBZS).
- 研究基和替代剂对聚合物特性的影响.
- 评估这些共聚合物在单聚合物和双聚合物太阳能电池中的性能.
主要方法:
- 合成二甲基醇替代的佐[1,2-b:4,5-b']二二甲基芬供体和单化二醇受体块.
- 同聚合物带间隙,HOMO和LUMO能量水平的表征.
- 使用PBDTFBZO和PBDTFBZS制造和测试单连接和合聚合物太阳能电池.
主要成果:
- 合成的共聚合物表现出大带间隙和深厚的HOMO/LUMO水平.
- 设备实现了改进的开通电压 (Voc),短路电流 (Jsc) 和填充系数 (FF).
- 单个设备的功率转换效率 (PCE) 达到了7.74%,双重设备的功率转换效率达到了9.40%.
结论:
- 添加二甲基和可以有效调整能量水平并提高太阳能电池的性能.
- PBDTFBZO和PBDTFBZS显示出作为高效的聚合物供体材料的潜力.
- 这些材料对开发大面积聚合物太阳能电池充满希望.
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