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紧紧绕的螺旋式碳纳米管的巨大的伸展性和可逆性
Jianyang Wu1, Jianying He, Gregory M Odegard
1NTNU Nanomechanical Lab, Norwegian University of Science and Technology (NTNU) , Trondheim N-7491, Norway.
Journal of the American Chemical Society
|September 11, 2013
概括
我们研究了螺旋式碳纳米管 (HCNTs),发现它们通过独特的变形机制表现出显著的伸展性 (400-1000%) 和能量消耗,为先进的纳米设备提供了洞察力.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 计算化学的计算化学
背景情况:
- 3D图形纳米结构对纳米设备和能量吸收有很大的兴趣.
- 螺旋式碳纳米管 (HCNTs) 由于其独特的特性,是有前途的候选者.
研究的目的:
- 为了研究紧紧绕的HCNT的拉伸不稳定性和可逆性.
- 了解控制HCNT伸展性和能量消耗的变形机制.
主要方法:
- 用原子模拟来研究在拉伸下HCNT的行为.
- 分析重点是卷轴间范德瓦尔斯 (vdW) 相互作用和缺陷诱导的约束.
主要成果:
- 超高度体通过尺寸依赖的机制表现出广泛的伸展性 (400-1000%):小型超高度体的多米诺骨折和大型超高度体的逐步曲.
- 在高温下通过高度分布的骨折实现了非凡的伸展性.
- 循环拉伸模拟显示出明显的hysteresis循环和显著的能量消耗在大型HCNTs由于曲和VDW债券恢复.
结论:
- 该研究提供了对混合CNT结构中高可塑性和优异可逆性的起源的物理洞察.
- 这些发现突显了HCNTs在先进的能吸收材料和纳米设备中的潜力.
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