土壤细菌的HONO排放是大气反应性的主要来源
R Oswald1, T Behrendt, M Ermel
1Biogeochemistry Department, Max Planck Institute for Chemistry, Mainz, Germany. robert.oswald@mpic.de
概括
土壤微生物释放大量的酸 (HONO),这是一个重要的大气化合物,有助于循环. 这种以前被低估的土壤衍生的HONO影响大气化学和土壤的气损失.
科学领域:
- 环境科学 环境科学
- 土壤科学 土壤科学
- 大气化学 大气化学
背景情况:
- 从土壤中化物 (NO2(-)) 中释放的酸 (HONO) 被建议作为大气中HONO和基 (OH) 的来源.
- 土壤衍生的HONO在生物地球化学和大气循环中的定量意义仍然不清楚.
研究的目的:
- 调查土壤衍生的HONO排放的作用和规模.
- 为了确定氨氧化细菌是否直接导致超出平衡预测的HONO释放.
主要方法:
- 实验室实验使用来自干旱和耕地地区的非酸性土壤.
- 量化反应性排放,包括HONO和氧化 (NO).
- 评估HONO释放与土壤酸和亨利定律平衡的关系.
主要成果:
- 来自测试土壤的HONO排放量与氧化 (NO) 的排放量相当.
- 发现氨氧化细菌直接释放HONO的量超过了基于平衡的预期.
- 这种微生物释放代表了循环的重要,以前未被考虑的途径.
结论:
- 土壤衍生的HONO是反应性排放的重要组成部分,与NO相当.
- 微生物活动,特别是氨氧化细菌,是大气HONO的直接和重要来源.
- 这一过程代表了土壤的额外损失和大气反应性的来源,影响了循环的动态.
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