磁极的确定和强度的记忆效应在一个Dy (III) 基单离子磁铁溶解后
Tamyris T da Cunha1, Julie Jung, Marie-Emmanuelle Boulon
1Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS-Université de Rennes 1 , 263 Avenue du Général Leclerc, 35042 Rennes Cedex, France.
Journal of the American Chemical Society
|October 17, 2013
概括
在固态和溶液状态下,[Dy(tta) 3(L) 复合体作为单离子磁铁起作用. 这种强大的磁性材料在溶液中保持其存储效应,直至4K.
科学领域:
- 协调化学 协调化学
- 磁电化学 磁电化学 磁电化学
- 材料科学 材料科学 材料科学
背景情况:
- 单离子磁铁 (SIM) 对于开发分子磁性材料至关重要.
- 了解控制磁性异构的因素是设计高效SIM的关键.
- 调查SIM在溶液中的行为对于潜在的应用很重要.
研究的目的:
- 为了合成和表征[Dy(tta) 3(L) ]复合体.
- 在晶体和溶液阶段研究[Dy(tta) 3(L) 复合物的磁性和异构性.
- 为了评估复合物的强度和记忆效应的持久性.
主要方法:
- 合成和单晶X射线衍射的[Dy(tta) 3(L) ]复合体.
- 可变温度直流 (dc) 和交流电 (ac) 磁感应度的测量.
- 振动样本磁力测量 (VSM) 和磁圆二元化 (MCD) 测量.
- 密度函数理论 (DFT) 计算用于理论磁性异性质分析.
主要成果:
- [Dy(tta) 3(L) ] 复合体表现出单离子磁铁在晶体和溶液状态中的行为.
- 实验和理论磁性异构轴显示出极好的一致性,与协调球中的电负原子对齐.
- 测量VSM和MCD证实了复合物的稳定性,证明了在溶液中持续的记忆效应到4K.
结论:
- [Dy(tta) 3(L) ] 复合体是一个有前途的单离子磁铁,具有强大的性能.
- 磁性异构轴的对齐为SIM的设计原则提供了洞察力.
- 存储效应在溶液中的持久性为基于溶液的磁性应用提供了可能性.
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