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Updated: May 6, 2026

Solid-phase Synthesis of [4.4] Spirocyclic Oximes
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模块化介质子学:了解和控制Münchnone衍生物的1,3-双极循环添加中的区域选择性

Marie S T Morin1, Daniel J St-Cyr, Bruce A Arndtsen

  • 1Department of Chemistry, McGill University , 801 Sherbrooke Street West, Montréal, Quebec H3A 2K6, Canada.

Journal of the American Chemical Society
|October 19, 2013
PubMed
概括

像Münchnones和phospha-Münchnones这样的介质1,3-二极体提供了pyrroles的模块化合成. 它们在与基因的循环添加中的反应性和区域选择性由基因电子和过渡状态能量控制.

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