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过渡状态的和对n-基的解中的反应性和选择性的影响

David W Flaherty1, Enrique Iglesia

  • 1Department of Chemical Engineering, University of California at Berkeley , Berkeley, California 94720, United States.

Journal of the American Chemical Society
|November 26, 2013
PubMed
概括

度,而不是度,决定了金属催化剂上的n-基中的C-C键裂变. 这项研究解释了链条长度和旋转如何影响键断裂,这是碳化合物解的关键因素.

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