基于烯胺衍生物的高效无机有机混合矿太阳能电池作为穿孔输送材料
Nam Joong Jeon1, Jaemin Lee, Jun Hong Noh
1Division of Advanced Materials, Korea Research Institute of Chemical Technology , 141 Gajeong-Ro, Yuseong-Gu, Daejeon 305-600, Republic of Korea.
Journal of the American Chemical Society
|December 10, 2013
概括
新的烯衍生物在矿太阳能电池中作为高效的孔载材料 (HTM) 起作用. 二烯衍生品Py-C实现了12.4%的功率转换效率,显示了未来太阳能电池应用的前景.
科学领域:
- 材料科学 材料科学 材料科学
- 有机化学 有机化学
- 太阳能光伏发电是如何实现的
背景情况:
- 矿太阳能电池需要高效的孔输送材料 (HTM) 才能达到最佳性能.
- 开发新的HTM对于推进太阳能电池技术至关重要.
- 皮雷尼衍生品为设计新的HTM提供了一个有前途的支架.
研究的目的:
- 为了合成和表征新的N,N-di-p-甲基胺替代的烯衍生物.
- 为了研究这些烯衍生物的光学和电子特性.
- 为了评估它们在矿太阳能电池中作为HTM的性能.
主要方法:
- 使用NMR光谱学,质谱学和元素分析进行合成和表征.
- 通过紫外线/紫外线光谱学和循环电压测量进行光学和电子性能调查.
- 半孔TiO2/CH3NH3PbI3/HTMs/Au太阳能电池的制造和测试.
主要成果:
- 三种烯衍生物成功合成和表征.
- 烯衍生物Py-C在太阳能电池中表现出12.4%的功率转换效率.
- 在Py-C中,短路电流密度为20.2 mA/cm2和开放电路电压为0.886 V.
- 性能与已确定的螺旋-OMeTAD HTM. 的性能相当.
结论:
- 合成的烯衍生物是矿太阳能电池的有效HTM.
- 二烯衍生物Py-C显示出高效太阳能转换的巨大潜力.
- 这项工作有助于开发用于下一代光伏的先进材料.
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