在环境条件下,乙烯由烯的可逆复合
Felicitas Lips1, James C Fettinger, Akseli Mansikkamäki
1Department of Chemistry, University of California , One Shields Avenue, Davis, California 95616, United States.
新的烯从烯和乙烯中合成. 西里兰4自发释放乙烯,表明具有 -24.9 kJ/mol 的计算自由协同能量的可逆反应.
科学领域:
- 有机化学 有机化学
- 主要组元素化学主要组元素化学
背景情况:
- 烯是具有双价原子的反应性物种.
- 酸是含有的三分环.
研究的目的:
- 为了合成和表征从无菌阻碍的丝烯中衍生的新型丝烯.
- 为了研究这些矿的稳定性和分解途径.
主要方法:
- 锡烯与乙烯气体的反应.
- 可变温度1HNMR光谱用于热力学分析.
- 计算研究以阐明反应机制.
主要成果:
- 合成了两个新型酸盐,即 (Ar(Me6) S) 2SiCH2CH2和 (Ar(Pr(i) 4) S) 2SiCH2CH2.
- 烯4在室温下表现出自发的乙烯演变.
- 范特霍夫分析确定了silirane 4的自由协同能量为-24.9(2.5) kJ/mol.
- 计算建模支持实验结果,预测了类似的自由能量和54kJ/mol的活性能量.
结论:
- 固体大容量替代品对锡利的影响锡利的稳定性.
- 观察到的乙烯演变表明一种可逆的烯-烯平衡.
- 这项研究提供了关于silirane分解的热力学和动力学的见解.
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