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Updated: May 4, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
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Published on: February 7, 2017

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定期可点击的聚合物:研究链内自我分离诱导的折叠,结晶和中相形成

Joydeb Mandal1, S Krishna Prasad, D S Shankar Rao

  • 1Department of Inorganic and Physical Chemistry, Indian Institute of Science , Bangalore-560012, India.

Journal of the American Chemical Society
|January 18, 2014
PubMed
概括

具有明显的基和基细分的新型聚合物被合成并自组装成独特的层状纳米结构. 这些材料提供了对形态的精确控制,使得先进的纳米结构聚合物开发成为可能.

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Polymer Classification: Crystallinity

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The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
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Polymer Classification: Architecture

Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
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Step-growth or condensation polymerization is a stepwise reaction of bi or multifunctional monomers to form long-chain polymers. As all the monomers are reactive, most of the monomers are consumed at the early stages of the reaction to form small chains of reactive oligomers, which then combine to form long polymer chains in the late stages. Hence, the reaction has to proceed for a long time to achieve high molecular weight polymers.
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