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Updated: May 3, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals

Published on: April 19, 2019

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通过两个周期性氨基碳稳定一个-键

Kartik Chandra Mondal1, Prinson P Samuel, Herbert W Roesky

  • 1Institut für Anorganische Chemie, Georg-August-Universität , Tammannstraße 4, 37077 Göttingen, Germany.

Journal of the American Chemical Society
|January 21, 2014
PubMed
概括

这项研究合成了一种新型的-碳复合物, (Me2-cAAC:) 2Co2,其中处于零氧化状态. 该复合体呈现单元基态,并经历可逆的氧化还原反应,形成稳定的基离子,在氧化状态下显著的Co-Co键缩短.

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Preparation of 6-aminocyclohepta-2,4-dien-1-one Derivatives via Tricarbonyltroponeiron07:56

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相关概念视频

Carbocations02:10

Carbocations

Carbocations are one of the reaction intermediates formed during several nucleophilic substitutions or elimination reactions. A carbocation is an electron-deficient species with the central carbon atom having six electrons and three bonded atoms. The central carbon in a carbocation is sp2 hybridized with trigonal planar geometry. It has an empty p orbital perpendicular to the plane of the structure that can accept electrons. Thus, carbocations act as strong electrophiles and may react with any...
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Alkenes via Reductive Coupling of Aldehydes or Ketones: McMurry Reaction

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Structural Isomerism

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