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形诱导的远程甲基-C-H激活氨基的氨基

Ri-Yuan Tang1, Gang Li1, Jin-Quan Yu1

  • 1Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA.

Nature
|March 14, 2014
PubMed
概括

研究人员开发了一种可回收的模板,用于选择性碳- (C-H) 功能化,使得远距离的甲基-C-H键在11个位置之外的反应成为可能. 这一突破克服了针对C-H激活的挑战,特别是对于几何难以接近的债券.

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