三角形和六角形分子项链的自组装.
Shijun Li1, Jianying Huang, Fengyan Zhou
1College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University , Hangzhou 310036, P. R. China.
Journal of the American Chemical Society
|April 10, 2014
概括
研究人员简化了复杂的连锁系统,使用自我组装和主机-客户化学. 这种方法有效地创造了 [4] 和 [7] 的分子项链,证明了先进的超分子化学.
科学领域:
- 超分子化学 超分子化学
- 有机化学 有机化学
背景情况:
- 连锁系统是复杂的分子架构.
- 自组装为它们的合成提供了一个简化的途径.
- 正角自组合和主机-客户复杂化是强大的工具.
研究的目的:
- 通过结合方法合成 [4] 和 [7] 的分子项链.
- 为了在金属循环形成和宿主-客人相互作用中使用bis (pyridinium) 动机.
- 为了证明多个分子组织成一个单一的超分子组合.
主要方法:
- 协调驱动的金属自行车自组装.
- 皇冠-以太主机-客户复合使用1,2-bis(pyridinium) 乙/dibenzo[24]皇冠-8识别图案.
- 适应 bis ((pyridinium) 图案变成一个半固的二氧基供体构建块.
主要成果:
- 成功合成了 [4] 和 [7] 的分子项链.
- 形成三角形和六角形的金属循环.
- 从三个独特的物种组织多达18个分子成一个单一的超分子组合.
结论:
- 协调驱动的自我组装和宿主-客人化学的组合简化了复杂连锁系统的形成.
- 经过调整的bis (pyridinium) 图案有效地整合了结构和识别功能.
- 这种方法为构建复杂的超分子架构提供了一个多功能平台.
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