酸加载亚 (-NN-) 基共价有机框架用于质子导电
Suman Chandra1, Tanay Kundu, Sharath Kandambeth
1Physical/Materials Chemistry Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411008, India.
Journal of the American Chemical Society
|April 25, 2014
概括
合成了化学稳定的共价有机框架 (COF),并证明了其高稳定性. 这些新材料显示出作为质子导电材料的前景,这是COF的首次.
科学领域:
- 材料科学 材料科学 材料科学
- 化学 化学 化学
- 纳米技术纳米技术
背景情况:
- 联有机框架 (COF) 是具有可调节性质的晶体多孔聚合物.
- 开发稳定的COF用于能源应用是一个正在进行的研究领域.
研究的目的:
- 合成新的,化学稳定的功能性COFs.
- 为了研究这些COF的质子导电性,特别是在兴奋剂后.
主要方法:
- 在三甲基 (Tp) 和4,4'-阿佐氨 (Azo) 或4,4'-二氨乙烯 (Stb) 之间发生希夫基反应.
- 合成的COFs (Tp-Azo和Tp-Stb) 的表征.
- 用H3PO4对Tp-Azo进行兴奋剂,以评估质子导电性.
主要成果:
- 成功合成了两种新的COF,即Tp-Azo和Tp-Stb.
- 这两种COF在水,酸性和基本条件下都表现出高化学稳定性.
- 用H3PO4合的TP-Azo在水和无水两种状态下都显示出显著的质子导电性.
结论:
- 合成的COF具有出色的化学稳定性.
- 本书介绍了COF作为质子导体材料的第一份报告.
- 这些发现为电化学能源应用中COF开辟了新的途径.
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