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Types Of Superconductors01:28

Types Of Superconductors

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A superconductor is a substance that offers zero resistance to the electric current when it drops below a critical temperature. Zero resistance is not the only interesting phenomenon as materials reach their transition temperatures. A second effect is the exclusion of magnetic fields. This is known as the Meissner effect. A light, permanent magnet placed over a superconducting sample will levitate in a stable position above the superconductor. High-speed trains that levitate on strong...
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A substance that reaches superconductivity, a state in which magnetic fields cannot penetrate, and there is no electrical resistance, is referred to as a superconductor. In 1911, Heike Kamerlingh Onnes of Leiden University, a Dutch physicist, observed a relation between the temperature and the resistance of the element mercury. The mercury sample was then cooled in liquid helium to study the linear dependence of resistance on temperature. It was observed that, as the temperature decreased, the...
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Theory of Metallic Conduction01:17

Theory of Metallic Conduction

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The conduction of free electrons inside a conductor is best described by quantum mechanics. However, a classical model makes predictions close to the results of quantum mechanics. It is called the theory of metallic conduction.
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
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A Single-Component System01:24

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In the field of chemistry, the terms "component" and "phase" hold significant importance. A component refers to a chemically distinct substance in a system that has specific properties. It is chemically homogeneous, meaning it has the same properties throughout. For example, in a mixture of salt and water, both salt and water are considered separate components because they have different chemical properties.On the other hand, a phase is a form of matter that has a consistent chemical...
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Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
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Comparison of Two Different Synthesis Methods of Single Crystals of Superconducting Uranium Ditelluride
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一个单元分子超导体.

HengBo Cui1, Hayao Kobayashi, Shoji Ishibashi

  • 1Condensed Molecular Materials Laboratory, RIKEN , Wako-shi, Saitama 351-0198, Japan.

Journal of the American Chemical Society
|May 13, 2014
PubMed
概括
此摘要是机器生成的。

在高压下 (大约7.5-8.7GPa) 在分子导体[Ni(hfdt) 2中出现超导. 这种从绝缘状态到超导状态的过渡与电子带结构的压力诱导变化有关.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 凝聚物质物理学 凝聚物质物理学
  • 固态化学 固态化学

背景情况:

  • 单元分子导体对电子应用具有前景.
  • 化合物[Ni(hfdt) 2在环境压力下表现出半导体特性.
  • 了解压力效应对于调整材料特性至关重要.

研究的目的:

  • 为了研究阻力在[Ni(hfdt) 2中的压力依赖性.
  • 为了确定压力诱导的超导过渡.
  • 阐明晶体结构,电子带结构和超导之间的关系.

主要方法:

  • 四探头电阻测量高达~10 GPa使用钻石细胞.
  • 在高压下 (6-11 GPa) 进行晶体和电子带结构的第一原理计算.

主要成果:

  • 低温绝缘阶段在7.5GPa以上被抑制.
  • 超导过渡观察到大约7.5-8.7GPa,最大Tc为5.5K.
  • 计算显示半导体带结构高达6GPa,电子和孔费米表面出现在8GPa.

结论:

  • 高压会在[Ni(hfdt) 2中诱导一个超导相.
  • 超导的出现与绝缘相的抑制和费米表面的出现有关.
  • 第一原则的计算支持了对压力诱导的电子结构变化的实验观测.