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相关概念视频

Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Weak Acid Solutions04:02

Weak Acid Solutions

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Few compounds act as strong acids. A far greater number of compounds behave as weak acids and only partially react with water, leaving a large majority of dissolved molecules in their original form and generating a relatively small amount of hydronium ions. Weak acids are commonly encountered in nature, being the substances partly responsible for the tangy taste of citrus fruits, the stinging sensation of insect bites, and the unpleasant smells associated with body odor. A familiar example of a...
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Acid Halides to Alcohols: LiAlH4 Reduction01:19

Acid Halides to Alcohols: LiAlH4 Reduction

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Acid halides are reduced to alcohols in the presence of a strong reducing agent like lithium aluminum hydride.
The mechanism proceeds in three steps. First, the nucleophilic hydride ion attacks the carbonyl carbon of the acid halide to form a tetrahedral intermediate. Next, the carbonyl group is re-formed, and the halide ion departs as a leaving group, generating an aldehyde. A second nucleophilic attack by the hydride yields an alkoxide ion, which, upon protonation, gives a primary alcohol as...
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Protocol of Electrochemical Test and Characterization of Aprotic Li-O2 Battery
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一种用于氧电池的溶液相双功能催化剂.

Dan Sun1, Yue Shen, Wang Zhang

  • 1State Key Laboratory of Material Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology , Wuhan, Hubei 430074, China.

Journal of the American Chemical Society
|May 16, 2014
PubMed
概括

铁酸 (FePc) 在氧电池中起到穿作用,通过促进没有直接碳接触的反应来提高性能. 这种分子穿方法可能使可充电空气电池成为现实.

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科学领域:

  • 电化学 电化学 电化学
  • 材料科学 材料科学 材料科学
  • 储能 储能 储能 储能 储能 储能

背景情况:

  • 氧电池提供高能量密度,但在阴极反应方面面临挑战.
  • 固体催化剂本身就难以促进空气阴极上的多相电化学反应.

研究的目的:

  • 调查铁亚 (FePc) 作为氧电池中的分子穿器的使用.
  • 通过解决阴极反应限制,提高氧电池的电化学性能.

主要方法:

  • 在有机电解质中溶解铁酸 (FePc).
  • 使用FePc来运送超氧化物种 (O2-) 和电子.
  • 在阴极上观察过氧化 (Li2O2) 的生长和分解.

主要成果:

  • 在导体表面和Li2O2.2.之间,FePc有效地运送O2和电子.
  • 过氧化物 (Li2O2) 的生长和分解发生在没有与碳直接接触的情况下.
  • 在氧电池系统中观察到增强的电化学性能.

结论:

  • 催化活性分子穿器,如FePc,可以克服氧电池阴极的限制.
  • 使用分子航天飞机是开发实用的可充电空气电池的一个有希望的策略.