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Updated: Apr 29, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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热化学洞察 CO 通过 [Re(CO) ](+) 和 [Mn(CO) ](+) 复合物降解为 CH3OH 的过程

Eric S Wiedner1, Aaron M Appel

  • 1Physical Sciences Division, Pacific Northwest National Laboratory , P.O. Box 999, K2-57, Richland, Washington 99352, United States.

Journal of the American Chemical Society
|May 24, 2014
PubMed
概括

了解一氧化碳 (CO) 降解为甲醇 (CH3OH) 的热力学障碍至关重要. 该研究确定H2添加到[CpRe(PPh3) ((NO) ((CO) ((+) 作为主要障碍,有潜力通过连接体和金属变化进行优化.

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