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Updated: Apr 28, 2026

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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引入π复合在有孔的芳香框架中,以对乙烯的高度选择性吸附在乙上

Baiyan Li1, Yiming Zhang, Rajamani Krishna

  • 1Department of Chemistry, University of South Florida , 4202 E. Fowler Avenue, Tampa, Florida 33620, United States.

Journal of the American Chemical Society
|June 6, 2014
PubMed
概括

这项研究将π-复杂化引入多孔芳香框架 (PAF) 中,以增强乙烯捕获. 具有Ag (I) 功能化的PAF-1-SO3Ag具有优越的乙烯/乙选择性,使得高纯度乙烯的生产成为可能.

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Aromatic Hydrocarbon Anions: Structural Overview

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The coupling interactions of nuclei across four or more bonds are usually weak, with J values less than 1 Hz. While these are usually not observed in spectra, the presence of multiple bonds along the coupling pathway can result in observable long-range coupling.
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