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一个电子介导的2.3-disiladicarbene的重新排列

Kartik Chandra Mondal1, Prinson P Samuel, Herbert W Roesky

  • 1Institut für Anorganische Chemie, Georg-August-Universität , Tammannstrasse 4, 37077 Göttingen, Germany.

Journal of the American Chemical Society
|June 10, 2014
PubMed
概括

研究人员合成了一种稳定的disiladicarbene化合物,具有-双键. 进一步减少产生了重新排列的产物和盐,突出显示了基离子中间体的反应性.

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