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Updated: Apr 27, 2026

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
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热不可切换的分子磁铁Cu (hfac) 2L (i-Pr) 的光交换,通过稳态和时间分辨率的电子偏磁共振证明了这一点

Irina Yu Barskaya1, Evgeny V Tretyakov, Renad Z Sagdeev

  • 1International Tomography Center SB RAS , Institutskaya str. 3a, 630090 Novosibirsk, Russia.

Journal of the American Chemical Society
|June 25, 2014
PubMed
概括

这项研究引入了一种新的铜氧化物分子磁铁,Cu (hfac) 2L (i-Pr),表现出可光切换的行为. 这种材料可以通过光诱导进入一个超稳定的自旋状态,为新的光交换应用开辟了道路.

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Colors and Magnetism03:02

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Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
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