强度合的Pd纳米四面体/氧化物纳米板混合体,具有增强的催化活性和稳定性,作为氧降低电催化剂
Yizhong Lu1, Yuanyuan Jiang, Xiaohui Gao
1State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences , Changchun 130022, Jilin China.
Journal of the American Chemical Society
|July 24, 2014
概括
开发新的-氧化物混合催化剂为氧降解反应 (ORR) 提供了低成本,高活性的解决方案. 这些先进的材料证明了燃料电池和电池的卓越稳定性和性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 纳米技术 纳米技术
背景情况:
- 开发具有成本效益和耐用的催化剂用于氧降解反应 (ORR) 对能源应用至关重要.
- 目前的催化剂在活动,稳定性和成本方面经常面临挑战.
研究的目的:
- 通过使用有机I前体,合成强度合的-氧化物纳米板混合物 (Pd/W18O49).
- 为了提高ORR的纳米晶体的电催化活性和稳定性.
主要方法:
- 通过直接核化,生长和定Pd四面体纳米晶体在W18O49纳米片上合成Pd/W18O49杂交物.
- 使用X射线光电子谱学和高分辨率传输电子显微镜进行表征.
- 在性溶液中的催化性能的电化学分析.
主要成果:
- 与没有支持的Pd纳米晶体和W18O49.9相比,Pd/W18O49混合体表现出明显更高的活性和更高的稳定性.
- 性能超过了 (Pt) 在性介质中的ORR.
- 增强的活性和耐用性归因于Pd四面体和W18O49支之间强烈的相互作用.
结论:
- 开发了一种新的策略,用于合成具有强大的化学和电气合的金属支持混合催化剂.
- Pd/W18O49混合体代表了燃料电池和金属空气电池的纳米电催化剂的一个有希望的类别.
- 这种方法为设计具有改进ORR性能的先进电催化剂提供了机会.
更多相关视频
相关概念视频
Catalysis
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
EDTA: Chemistry and Properties
Polydentate ligands are most widely used in complexometric titrations because they form more stable complexes with the metal ions than mono- or bidentate ligands due to the chelate effect. Examples of polydentate ligands are ethylenediaminetetraacetic acid (EDTA), crown ethers, and cryptands. The most important feature of optimal polydentate ligands is the ability to form 1:1 complexes in a single-step process. Amino carboxylic acid derivatives are frequently used as complexing agents. EDTA is...
EDTA: Auxiliary Complexing Reagents
EDTA titrations are usually carried out in highly basic conditions, where the fully deprotonated form of EDTA, Y4−, actively complexes with the free metal ions in the solution. Several metal ions precipitate as hydrous oxide (hydroxides, oxides, or oxyhydroxides) under these conditions, lowering the concentration of free metal ions in the solution. For this reason, auxiliary complexing agents or ligands such as ammonia, tartrate, citrate, or triethanolamine are used in EDTA titrations to...


