温度依赖的可逆p-n-p类型导电切换与半导体AgCuS的热功率的巨大变化
Satya N Guin1, Jaysree Pan, Arghya Bhowmik
1New Chemistry Unit and §Theoretical Sciences Unit, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR) , Jakkur P.O., Bangalore 560064, India.
Journal of the American Chemical Society
|August 20, 2014
概括
一种新型的半导体,银铜硫化物 (AgCuS),在其超声波相变时显示可逆的p-n-p切换和大热功率变化. 这种材料非常适合在室温附近的温度或电压控制设备.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 凝聚物质物理学 凝聚物质物理学
背景情况:
- 半导体对于晶体管和传感器等电子设备至关重要.
- 对于温度梯度操作开关的新型无机材料越来越感兴趣.
研究的目的:
- 研究银铜硫化物 (AgCuS) 作为温度控制半导体开关材料的潜力.
- 了解其独特的电热性能背后的机制.
主要方法:
- 取决于温度的同步光子粉体X射线衍射射线.
- 热容量测量测量热容量测量
- 拉曼光谱法 拉曼光谱法 拉曼光谱法
- 定子消灭光谱学 定子消灭光谱学
- 第一个原则计算计算.
主要成果:
- 在其超离子相位过渡 (~364 K) 时,AgCuS表现出利的,可逆的p-n-p类型导电切换.
- 观察到热力 (~1757μV K-1) 的巨大变化.
- 在300-550K范围内的超低导热率允许保持温度梯度.
- 第一原则计算显示了电气和声声传输的脱.
结论:
- AgCuS显示出独特的特性组合,使其适合用于新型电子设备.
- 温度依赖的开关行为非常适合在室温附近的温度或电压变化下运行的二极管或晶体管.
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