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Updated: Apr 25, 2026

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
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寻找单片裂变的小分子:一个异质原子替代策略

Tao Zeng1, Nandini Ananth, Roald Hoffmann

  • 1Department of Chemistry and Chemical Biology, Cornell University , Ithaca, New York 14853, United States.

Journal of the American Chemical Society
|August 21, 2014
PubMed
概括

研究人员通过战略性地用和替代碳原子来设计新的单片裂变 (SF) 染色体. 这种方法平衡了有效的能源转换的关键激进性和稳定性.

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A bond is formed between two atoms by sharing two electrons. When this bond is broken by supplying sufficient energy, either two electrons can be taken up by one atom forming ions by the cleavage called heterolysis, or the two electrons are shared by two atoms, with one each creating radicals by the cleavage called homolysis.
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A proton M that is coupled to a proton X results in doublet signals for M. However, NMR-active nuclei can be simultaneously coupled to more than one nonequivalent nucleus. When M is coupled to a second proton A, such as in styrene oxide, each peak in the doublet is split into another doublet.
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