一个分子三叶草结的lanthanide模板合成
Jean-François Ayme1, Guzmán Gil-Ramírez, David A Leigh
1School of Chemistry, University of Manchester , Oxford Road, Manchester M13 9PL, United Kingdom.
Journal of the American Chemical Society
|September 9, 2014
概括
研究人员使用三种连接体围绕着一个类离子创建了一个分子三叶草结. 然后将这个复合体转化为纯有机结,证明了复杂分子结构的新合成.
科学领域:
- 超分子化学 超分子化学
- 有机合成 有机合成
- 协调化学 协调化学
背景情况:
- 兰化物离子在协调化学中至关重要.
- 分子结是复杂的拓结构,具有潜在的应用.
- 2,6-二二二胺联体提供了多功能协调特性.
研究的目的:
- 为了合成一种新的分子三叶草结,使用兰化物模板自组装.
- 通过环闭式氨酸转化,研究多连接体复合物的循环化.
- 为了实现脱金属化,生成一个完全有机的分子结.
主要方法:
- 三个2,6-二二二胺联体围绕一个兰坦化离子的协调.
- 环闭式烯转化为连接体循环.
- 使用四甲基化物进行脱.
主要成果:
- 形成一个兰他尼德-合体复合体.
- 在58%的收益率中成功循环转化为分子三叶草结.
- 在脱金属化后,有机三叶草结的定量生成.
结论:
- 开发了一种新的方法来合成复杂的分子三叶草结.
- 兰化物模板合成后的转化合成可以访问复杂的分子拓.
- 脱金属化步骤产生了一个纯有机的,大环分子结.
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