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Updated: Apr 23, 2026

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs

Published on: January 17, 2020

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虚空的天性伊米达酸框架纳米球作为 [3+3] 循环添加反应的高效合作催化剂

Fang Zhang1, Yongyi Wei, Xiaotao Wu

  • 1The Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University , Shanghai 200234, China.

Journal of the American Chemical Society
|September 26, 2014
PubMed
概括

一种新型的空心极性伊米达酸框架 (ZIF-8-H) 纳米圈有效催化 [3+3] 循环添加反应. 这种强大的催化剂在化学合成中表现出高活性,稳定性和可回收性.

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Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
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