相关实验视频
Updated: Apr 22, 2026

16:20
Hyperpolarized Xenon for NMR and MRI Applications
Published on: September 6, 2012
19.3K
无极性MRI对比揭示了塑料晶体中增强的离子运输
Konstantin Romanenko1, Liyu Jin, Louis A Madsen
1Institute for Frontier Materials, Deakin University , Waurn Ponds Campus, 75 Pigdons Road, Geelong, Victoria 3220, Australia.
Journal of the American Chemical Society
|October 15, 2014
概括
有机离子塑料晶体 (OIPC) 显示出对固态电解质的前景. 它们的导电性高度依赖于微晶体对齐,可以通过热史来控制以提高性能.
科学领域:
- 固态化学 固态化学
- 材料科学是一种材料科学.
- 电化学 电化学 电化学
背景情况:
- 有机离子塑料晶体 (OIPC) 是像离子电池这样的设备的有望固态电解质.
- 它们的离子运输特性尚未完全理解,并且对热史敏感.
- 现有的研究缺乏对导电性的微观结构影响的详细理解.
研究的目的:
- 研究OIPC中微晶体方向和离子运输之间的关系.
- 探索一种新的表征方法,以了解塑料晶体中的域结构.
- 为电化学应用确定优化OIPC性能的方法.
主要方法:
- 固态磁共振成像 (MRI) 用于可视化微晶体的方向和粒度边界.
- 阻抗光谱法用于测量离子导电性.
- 控制的热处理 (从融中缓慢冷却) 的三乙 () 二 () 硫 () 胺 (P1222FSI) 样品.
主要成果:
- 在多晶OIPC中,MRI揭示了与粒粒边界方向相关的图像对比异构.
- 不同的热历史导致了微晶体对齐的显著变化.
- 从融中缓慢冷却诱导了首选的微晶体向,使导电率增加了一个数量级.
结论:
- 微晶体对齐显著影响OIPC中的离子运输.
- 控制的热处理可以优化OIPC微观结构并增强离子导电性.
- 固态MRI提供了一种新的方法来描述域结构,并指导固态导体的材料设计.
相关概念视频
Magnetic Resonance Imaging
7.5K
Magnetic resonance imaging (MRI) is a noninvasive medical imaging technique based on a phenomenon of nuclear physics discovered in the 1930s, in which matter exposed to magnetic fields and radio waves was found to emit radio signals. In 1970, a physician and researcher named Raymond Damadian noticed that malignant (cancerous) tissue gave off different signals than normal body tissue. He applied for a patent for the first MRI scanning device in clinical use by the early 1980s. The early MRI...
7.5K
Phase Contrast and Differential Interference Contrast Microscopy
9.3K
Phase-Contrast Microscopes
In-phase-contrast microscopes, interference between light directly passing through a cell and light refracted by cellular components is used to create high-contrast, high-resolution images without staining. It is the oldest and simplest type of microscope that creates an image by altering the wavelengths of light rays passing through the specimen. Altered wavelength paths are created using an annular stop in the condenser. The annular stop produces a hollow cone of...
In-phase-contrast microscopes, interference between light directly passing through a cell and light refracted by cellular components is used to create high-contrast, high-resolution images without staining. It is the oldest and simplest type of microscope that creates an image by altering the wavelengths of light rays passing through the specimen. Altered wavelength paths are created using an annular stop in the condenser. The annular stop produces a hollow cone of...
9.3K
Ionic Crystal Structures
17.8K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
17.8K
Crystal Field Theory - Octahedral Complexes
28.3K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
28.3K
Insensitive Nuclei Enhanced by Polarization Transfer (INEPT)
1.1K
Insensitive Nuclei Enhanced by Polarization Transfer (INEPT) is an advanced Nuclear Magnetic Resonance (NMR) technique specifically designed to detect and enhance the signals of low-abundance nuclei, such as carbon-13 and nitrogen-15, in small molecules. The fundamental principle behind INEPT is the transfer of polarization from a more abundant and highly polarizable nucleus, typically hydrogen-1, to the low-abundance nucleus of interest. This process effectively boosts the NMR signal of the...
1.1K
Plasticity
2.2K
Plasticity is the property where an object loses its elasticity and undergoes irreversible deformation, even after the deformation forces are eliminated. If a material deforms irreversibly without increasing stress or load, then this is called ideal plasticity. For example, when a force is applied to an aluminum rod, it changes its shape, but it does not return to its original shape once the force is removed. Plastic deformation or ductility is thus a permanent deformation or change in the...
2.2K

