自组装纳米纤维的客驱动膨胀通过空洞通道形成
Yanqiu Wang1, Zhegang Huang, Yongju Kim
1State Key Lab for Supramolecular Structure and Materials, College of Chemistry, Jilin University , Changchun 130012, China.
Journal of the American Chemical Society
|November 6, 2014
概括
研究人员创造了智能纳米纤维,当添加客分子时,它们会膨胀成螺旋状管道. 这种自组装过程利用可逆的非对应相互作用来实现可切换的纳米结构.
科学领域:
- 超分子化学 超分子化学
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
背景情况:
- 自组装依赖于可逆的非对应相互作用来创建动态的纳米结构.
- 纳米结构中的可切换毛孔为控制释放和传感应用提供了潜力.
研究的目的:
- 报告充气纳米纤维与可切换毛孔的自发形成.
- 研究这些纳米纤维中客体诱导的膨胀和孔隙形成的机制.
主要方法:
- 合成曲形状的芳香分子与胺单元和树枝.
- 通过配对二元堆叠观察自组装成纳米纤维的过程.
- 使用客分子 (p-phenylphenol) 触发和表征可逆膨胀到螺旋状管道.
主要成果:
- 通过自组装自发形成具有内空通道的纳米纤维.
- 纳米纤维的可逆膨胀成螺旋状管道,由p-phenylphenol客体封装诱导.
- 机制涉及通过结相互作用驱动的芳香核中的包装重组.
结论:
- 展示了一种创新方法,用于创建具有可切换毛孔的充气纳米纤维.
- 突出了客-响应式结相互作用在推动结构转型中的作用.
- 为设计具有可调节性质的智能纳米结构打开了道路.
相关概念视频
Batteries and Fuel Cells
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
Van de Graaff Generator
Van de Graaff generators (or Van de Graaffs) are devices used to demonstrate high voltage due to static electricity that can also be used for research. Robert Van de Graaff first built one in 1931 (based on original suggestions by Lord Kelvin) for use in nuclear physics research.
Van de Graaff uses both smooth and pointed surfaces, conductors, and insulators to generate large static charges and, hence, large voltages. A substantial excess charge can be deposited on the sphere because it moves...
Van de Graaff uses both smooth and pointed surfaces, conductors, and insulators to generate large static charges and, hence, large voltages. A substantial excess charge can be deposited on the sphere because it moves...
P-N junction
A p-n junction is formed when p-type and n-type semiconductor materials are joined together. At the interface of the p-n junction, holes from the p-side and electrons from the n-side begin to diffuse into the opposite sides due to the concentration gradient. This diffusion of carriers leads to a region around the junction where there are no free charge carriers, known as the depletion region. The charge density within the depletion region for the n-side and p-side can be described by the...
Metal-Semiconductor Junctions
The contact of metal and semiconductor can lead to the formation of a junction with either Schottky or Ohmic behavior.
Schottky Barriers
Schottky barriers arise when a metal with a work function (Φm) contacts a semiconductor with a different work function (Φs). Initially, electrons transfer until the Fermi levels of the metal and semiconductor align at equilibrium. For instance, if Φm > Φs, the semiconductor Fermi level is higher than the metal's before contact. The semiconductor's...
Schottky Barriers
Schottky barriers arise when a metal with a work function (Φm) contacts a semiconductor with a different work function (Φs). Initially, electrons transfer until the Fermi levels of the metal and semiconductor align at equilibrium. For instance, if Φm > Φs, the semiconductor Fermi level is higher than the metal's before contact. The semiconductor's...
Biasing of Metal-Semiconductor Junctions
Biasing metal-semiconductor junctions involves applying a voltage across the junction. Specifically, the metal is connected to a voltage source, while the semiconductor is grounded. This technique is essential for controlling the direction and magnitude of current flow in electronic devices, including diodes, transistors, and photovoltaic cells.
In Schottky junctions, where the semiconductor is n-type, applying a positive voltage to the metal relative to the semiconductor reduces its Fermi...
In Schottky junctions, where the semiconductor is n-type, applying a positive voltage to the metal relative to the semiconductor reduces its Fermi...


