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在盐中退化的核替代

Elizabeth V Jennings1, Kirill Nikitin, Yannick Ortin

  • 1Centre for Synthesis and Chemical Biology, School of Chemistry and Chemical Biology, University College Dublin , Dublin 4, Ireland.

Journal of the American Chemical Society
|November 12, 2014
PubMed
概括

在酸上发生退化化物替代通过两步机制,涉及五坐标中间体. 实验和计算研究揭示了影响这种重要的化学反应的能量障碍和硬质效应.

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