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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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作为主要组元素结合的硬币金属:碳化合物复合物的结构和结合[TM(cAAC) ]和[TM(cAAC) ] (TM = Cu, Ag, Au) (TM = Cu, Ag, Au)

Paul Jerabek1, Herbert W Roesky, Guy Bertrand

  • 1Fachbereich Chemie, Philipps-Universität Marburg , Hans-Meerwein-Strasse, D-35032 Marburg, Germany.

Journal of the American Chemical Society
|November 15, 2014
PubMed
概括

量子化学计算显示,周期性 (基) 氨基) 碳 (cAAC) 连接物在中形成更强的金属-连接物键[TM(cAAC) ]+) 比中性复合物[TM(cAAC) ]中形成更强的金属-连接物键. 相对论效应显著影响债券强度,黄金复合体在非相对论水平上显示较弱的债券.

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