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Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of PhosphorusI
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可逆的分子间E-H氧化添加到几何变形和结构动态的三化物中

Wei Zhao1, Sean M McCarthy, Ting Yi Lai

  • 1Department of Chemistry and ‡X-ray Crystallography Laboratory, Department of Biochemistry and Molecular Biology, The Pennsylvania State University , University Park, Pennsylvania 16802, United States.

Journal of the American Chemical Society
|November 18, 2014
PubMed
概括

在几何上受到限制的三坐标化合物在中表现出低能量反转. 这些化合物经过与O-H和N-H化合物的氧化添加,形成可逆五坐标 adducts.

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