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Updated: Apr 20, 2026

ARL Spectral Fitting as an Application to Augment Spectral Data via Franck-Condon Lineshape Analysis and Color Analysis
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优化光活性抗癌氧二-桥接二复合物的电子特性 (II,II)

Zhanyong Li1, Amanda David, Bryan A Albani

  • 1Department of Chemistry, Texas A&M University , College Station, Texas 77840, United States.

Journal of the American Chemical Society
|December 2, 2014
PubMed
概括

迪罗化合物与特定的皮里丁配体显示可调节的光反应性. 连接物修饰增强了光化疗的细胞毒性,诱导癌细胞的亡.

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Photochemical Electrocyclic Reactions: Stereochemistry

The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
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ROS generation is regulated and maintained at moderate levels necessary...
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