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Updated: Apr 19, 2026

Synthesis of pH Dependent Pyrazole, Imidazole, and Isoindolone Dipyrrinone Fluorophores using a Claisen-Schmidt Condensation Approach
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通过二元金属宏循环中的Ag-π相互作用,对二元级芳香客分子进行多点识别

Kenichiro Omoto1, Shohei Tashiro, Masumi Kuritani

  • 1Department of Chemistry, Graduate School of Science, The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan.

Journal of the American Chemical Society
|December 6, 2014
PubMed
概括

研究人员开发了一种新型的宏循环宿主,具有白银 (I) 中心和炭烯壁. 这种宿主通过银-π 相互作用有效地结合铁等芳香分子,形成具有高结合常数的稳定包含综合体.

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The Cope rearrangement is classified as a [3,3] sigmatropic shift in 1,5-dienes, leading to a more stable, isomeric 1,5-diene. The reaction involves a concerted movement of six electrons, four from two π bonds and two from a σ bond, via an energetically favorable chair-like transition state.
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Removing one hydrogen from the intervening CH2 group...
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