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Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
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perfluorinated aryl azides 的1,3-双极循环添加反应性与胺和压力双极的双极

Sheng Xie1, Steven A Lopez, Olof Ramström

  • 1Department of Chemistry, KTH-Royal Institute of Technology , Teknikringen 36, Stockholm, Sweden.

Journal of the American Chemical Society
|January 2, 2015
PubMed
概括

perfluoroaryl azides (PFAAs) 在与酶胺的循环添加中反应的速度明显快于酸. 这种增强的反应性源于PFAA.

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