一个酸复合物作为快速高效的生产催化剂
Lu Gan1, Thomas L Groy, Pilarisetty Tarakeshwar
1Department of Chemistry and Biochemistry, Arizona State University , Tempe, Arizona 85287, United States.
Journal of the American Chemical Society
|January 7, 2015
概括
一个新的复合物,Ni{\bdt}{\dppf}),有效地催化了质子减少到. 这种电催化剂在酸性溶液中表现出高活性,低超电位和稳定性,为生产提供了一个有前途的途径.
科学领域:
- 无机化学 无机化学
- 电触媒溶解是一种电触媒.
- 可持续能源 可持续能源
背景情况:
- 开发高效的电催化剂用于生产气对于可再生能源至关重要.
- 复合物有潜力作为地球上丰富的贵金属催化剂的替代品.
研究的目的:
- 报告一种新的S2P2协调复合物,Ni{\bdt}{\dppf},用于电催化性质子还原.
- 为了研究这种复合物的催化活性,效率和稳定性.
主要方法:
- 用电催化技术将质子减少为.
- 合成和特征的 [Ni(bdt) ((dppf) ] 复合体.
- 密度函数理论 (DFT) 计算以阐明催化机制.
主要成果:
- [Ni(bdt) ((dppf) ]复合体表现出快速和高效的催化剂,其周转频率为1240s(-1).
- 在低酸度下,为半活性达到265mV的超电位.
- 在酸性溶液和用弱酸催化中至少4小时的稳定性被证明.
结论:
- 新型复合物是生产的高效电催化剂.
- DFT计算支持一个机制,涉及中心的质子化.
- 催化剂的效率,稳定性和与弱酸运行的能力显示出实际应用的巨大潜力.
更多相关视频
相关概念视频
Catalysis
32.6K
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
32.6K
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
4.1K
Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
4.1K
Reduction of Alkenes: Catalytic Hydrogenation
15.3K
Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
15.3K
Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation
9.7K
Introduction
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
9.7K
Heterogeneous Catalysis
129
Heterogeneous catalysis involves a catalyst in a different phase from the reactants. It is a process where the catalyst and the reactants are in distinct phases, typically solid and gas or liquid.Most heterogeneous catalysts are metals, metal oxides, or acids. The list includes transition metals like iron (Fe), cobalt (Co), nickel (Ni), palladium (Pd), platinum (Pt), chromium (Cr), manganese (Mn), tungsten (W), silver (Ag), and copper (Cu). These metals possess partially vacant d orbitals that...
129
Reduction of Benzene to Cyclohexane: Catalytic Hydrogenation
6.6K
Unlike the easy catalytic hydrogenation of an alkene double bond, hydrogenation of a benzene double bond under similar reaction conditions does not take place easily. For example, in the reduction of stilbene, the benzene ring remains unaffected while the alkene bond gets reduced. Hydrogenation of an alkene double bond is exothermic and a favorable process. In contrast, to hydrogenate the first unsaturated bond of benzene, an energy input is needed; that is, the process is endothermic. This is...
6.6K


