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相关概念视频

Heterogeneous Catalysis01:22

Heterogeneous Catalysis

129
Heterogeneous catalysis involves a catalyst in a different phase from the reactants. It is a process where the catalyst and the reactants are in distinct phases, typically solid and gas or liquid.Most heterogeneous catalysts are metals, metal oxides, or acids. The list includes transition metals like iron (Fe), cobalt (Co), nickel (Ni), palladium (Pd), platinum (Pt), chromium (Cr), manganese (Mn), tungsten (W), silver (Ag), and copper (Cu). These metals possess partially vacant d orbitals that...
129
Catalysis02:50

Catalysis

32.6K
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
32.6K
Introduction to Mechanisms of Enzyme Catalysis01:13

Introduction to Mechanisms of Enzyme Catalysis

11.7K
For many years, scientists thought that enzyme-substrate binding took place in a simple "lock-and-key" fashion. This model stated that the enzyme and substrate fit together perfectly in one instantaneous step. However, current research supports a more refined view scientists call induced fit. The induced-fit model expands upon the lock-and-key model by describing a more dynamic interaction between enzyme and substrate. As the enzyme and substrate come together, their interaction causes...
11.7K
Introduction to Mechanisms of Enzyme Catalysis01:13

Introduction to Mechanisms of Enzyme Catalysis

10.3K
10.3K
Factors Influencing the Rate of Chemical Reactions01:22

Factors Influencing the Rate of Chemical Reactions

9.6K
A variety of factors influence the rate of chemical reactions. For a chemical reaction to happen, atoms must collide with enough energy to overcome the repulsion between their electrons. This energy is called activation energy. Factors influencing the rate of reaction either lower the activation energy or increase the likelihood of a successful collision.
Concentration and Pressure:
The more particles present within a given space, the more likely those particles are to bump into one another....
9.6K
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation02:17

Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

4.1K
Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
4.1K

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相关实验视频

Updated: Apr 18, 2026

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs

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电化学响应的异质催化剂用于控制反应动力学.

Xianwen Mao1, Wenda Tian, Jie Wu

  • 1Department of Chemical Engineering and ‡Department of Chemistry, Massachusetts Institute of Technology , 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.

Journal of the American Chemical Society
|January 8, 2015
PubMed
概括

我们开发了电化学响应异质催化剂 (ERHC),以精确控制反应速率. 这种方法为流动反应器的灵活反应管理提供了催化剂活性的持续调整.

科学领域:

  • 催化剂是一种催化剂.
  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学

背景情况:

  • 控制反应动力学对于化学过程至关重要.
  • 现有的响应性催化方法缺乏精确的控制和集成能力.
  • 电化学控制为可调节的催化提供了一个有希望的途径.

研究的目的:

  • 开发和演示一种新的电化学响应异质催化 (ERHC) 系统.
  • 为了实现对反应速度的连续和精确控制.
  • 展示该系统在批量和流量反应堆中的适用性.

主要方法:

  • 使用碳微纤维和氧化还原聚合物涂层制造混合型ERHC系统.
  • 利用迈克尔反应来研究依赖于氧化还原状态的动力学.
  • 应用电化学潜能来调节催化剂活动.
  • 执行用于流动反应堆集成的COMSOL模拟.

主要成果:

  • 证明了反应速率与应用电化学潜力的持续变化.
  • 观察到反应速率对电位的纳尔斯蒂安式依赖.
  • 在批量反应堆中展示了反应剂度-时间概况的操纵.

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Precise Electrochemical Sizing of Individual Electro-Inactive Particles

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  • 在流量反应堆中模拟灵活的空间和时间控制.
  • 结论:

    • ERHC提供了一个多功能平台,用于精确控制化学反应.
    • 该系统允许持续调整催化剂活动.
    • ERHC可以很容易地集成到流动反应堆中,用于先进的过程控制.