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Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
56.2K
Ionic Crystal Structures02:42

Ionic Crystal Structures

21.7K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
21.7K
Ionic Association01:28

Ionic Association

202
The ionic association is the association of oppositely charged ions in an electrolyte solution to form ion pairs. Bjerrum defined ion pairs as two oppositely charged ions whose electrostatic attraction exceeds the thermal energy of the system, typically expressed as 2kT. Electrostatic attraction depends on ionic charge, separation distance, and the dielectric constant of the medium. Thermal energy, represented by kT, reflects the tendency of ions to move independently due to molecular motion.
202
Types Of Superconductors01:28

Types Of Superconductors

1.9K
A superconductor is a substance that offers zero resistance to the electric current when it drops below a critical temperature. Zero resistance is not the only interesting phenomenon as materials reach their transition temperatures. A second effect is the exclusion of magnetic fields. This is known as the Meissner effect. A light, permanent magnet placed over a superconducting sample will levitate in a stable position above the superconductor. High-speed trains that levitate on strong...
1.9K
Trends in Lattice Energy: Ion Size and Charge02:54

Trends in Lattice Energy: Ion Size and Charge

27.8K
An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
27.8K
Theory of Strong Electrolytes01:23

Theory of Strong Electrolytes

114
The interionic forces of the strong electrolytes depend on the solvent's dielectric constant, which is the ability of a solvent to store electrical energy, based on its polarizability. and the solution's concentration. In high-dielectric solvents and in dilute solutions, weak electrostatic forces keep ions apart. However, in low-dielectric solvents or concentrated solutions, stronger interionic forces may cause ions to pair up as ionic doublets despite being fully ionized. The theory of strong...
114

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相关实验视频

Updated: Apr 18, 2026

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
06:44

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

Published on: March 24, 2018

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一个基于的Li7P2S8I超离子导体.

Ezhiylmurugan Rangasamy1, Zengcai Liu, Mallory Gobet

  • 1Center for Nanophase Materials Sciences, Oak Ridge National Laboratory , Oak Ridge, Tennessee 37831, United States.

Journal of the American Chemical Society
|January 21, 2015
PubMed
概括
此摘要是机器生成的。

一种新型的固态离子导体Li(7) P(2) S(8) I,表现出高达10V的显著电化学稳定性.该材料提高了离子电池的性能,并通过低温加工实现了工业采用.

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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature

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Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV
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Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV

Published on: December 29, 2016

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相关实验视频

Last Updated: Apr 18, 2026

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV
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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 固态化学 固态化学

背景情况:

  • 固态电解质对于下一代离子电池至关重要.
  • 同时实现高电化学稳定性和良好的离子导电性仍然是一个挑战.
  • 固有的氧化不稳定性往往限制了其在电化学系统中的使用.

研究的目的:

  • 开发一种具有增强电化学稳定的新型固态离子导体.
  • 调查加入在稳定材料和改善接口性能方面的作用.
  • 评估材料对潜在的工业应用的可加工性.

主要方法:

  • 合成Li(7)P(2)S(8)I固态导体从β-Li(3)PS(4) 和LiI.
  • 电化学稳定性窗口的确定使用循环电压测量到10V与Li/Li(+).
  • 用金属阳极对界面特性和离子导电性的评估.
  • 低温膜制造可加工性的评估.

主要成果:

  • 7P2S8I导体表现出极好的电化学稳定性,高达10V与/+).
  • 将纳入协调结构有效地抑制了其氧化不稳定性.
  • 该材料通过金属阳极表现出增强的稳定性,改进的界面动力学和高离子导电性.
  • 通过低温膜加工实现了密集膜的轻松制造.

结论:

  • 开发的Li(7)P(2)S(8)I固态导体为高压离子电池提供了一个有前途的解决方案.
  • 通过结构内置稳定是克服其电化学局限性的可行策略.
  • 该材料的可加工性和性能特性使其适用于工业规模的电池制造.