控制MoS2和WS2在溶液中的金属到半导体的过渡
Stanley S Chou1, Yi-Kai Huang, Jaemyung Kim
1Advanced Materials Laboratory, Sandia National Laboratories , Albuquerque, New Mexico 87185, United States.
Journal of the American Chemical Society
|January 23, 2015
概括
现在可以在有机溶剂中分散化学脱皮的二硫化物 (MoS2) 和二硫化物 (WS2) 板. 它们的半导体特性在溶液中可回收,使金属半导体过渡的轻松调整成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 化学 化学 化学
背景情况:
- 化-脱皮产生单层到几层的二硫化物 (MoS2) 和二硫化物 (WS2) 板.
- 这个过程将材料从半导体2H相转换为金属相.
- 恢复半导体性能通常需要在固体基板上进行高温回火.
研究的目的:
- 开发一种在高沸点有机溶剂中分散化学剥落的MoS2和WS2片的方法.
- 为了使半导体性质在溶液中直接恢复.
- 为了将化学脱皮的可扩展性与可调节的金属半导体过渡的基于溶液的加工联系起来.
主要方法:
- 剥落的MoS2和WS2板的表面功能化.
- 功能化板在高沸点有机溶剂中的分散.
- 在液体介质中可控地恢复半导体特性.
主要成果:
- 在有机溶剂中成功分散化学剥皮的MoS2片.
- 在溶液中证明可控制的半导体特性恢复.
- 建立了在液体介质中调金属半导体过渡的简单方法.
结论:
- 表面功能化使得皮MoS2和WS2的溶液处理成为可能.
- 在溶液中实现可控的半导体特性恢复.
- 这种方法提供了一种可扩展和简单的方法来调整过渡金属二二甲基的电子特性.
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