柱状的液晶金属巨圆.
Shin-ichiro Kawano1, Yukari Ishida, Kentaro Tanaka
1Department of Chemistry, Graduate School of Science, Nagoya University , Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan.
Journal of the American Chemical Society
|February 7, 2015
概括
研究人员合成了新的宏环分子及其金属复合体,表现出热热的柱状液晶态行为. 这些金属宏观循环在广泛的温度范围内表现出自我组装成流体相.
科学领域:
- 超分子化学 超分子化学
- 材料科学 材料科学 材料科学
- 协调化学 协调化学
背景情况:
- 动态共价化学使得大小选择性合成的宏循环配体.
- 宏循环具有一个大,对称的腔和一个56π平面环系统.
研究的目的:
- 合成新的宏环分子及其金属复合物.
- 为了研究它们的热热型柱状液晶态行为.
主要方法:
- 用于配体合成的动态共价化学.
- 进行X射线衍射,差分扫描热度计和偏光光学显微镜以进行表征.
- 将Ni(2+) 和Cu(2+) 离子纳入盐联体.
主要成果:
- 合成了离散的,高度对称的宏循环,具有9 Å腔.
- 在宏观循环中形成正方形平面金属复合体.
- 观察到自组装成高流动性的柱状液晶相.
- 证明了外围基链会影响液晶特性和温度范围.
结论:
- 这些是第一个报告的大型空洞区域的宏环金属复合体的热热型柱状液晶.
- 与没有金属的类似物相比,金属宏环表现出增强的液晶温度范围.
- 这项研究强调了宏环金属复合物的潜力,用于开发先进的液晶材料.
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