光发光温度计基于相位过渡酸盐,具有不寻常的结构障碍
Duarte Ananias1, Filipe A Almeida Paz, Dmitry S Yufit
1Departments of Chemistry and ‡Physics, CICECO Aveiro Institute of Materials, University of Aveiro , 3810-193 Aveiro, Portugal.
Journal of the American Chemical Society
|February 10, 2015
概括
新型发光酸盐,Na[LnSiO4],显示结构相位过渡低于100K. 这种过渡使得高灵敏的光学温度计可用于冷温度.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 晶体学 晶体学是指结晶学.
背景情况:
- 热水合成可以创造具有独特结构的新型材料.
- 含有兰他尼德的酸盐因其光物理性质而引起人们的兴趣.
研究的目的:
- 报告新型Na[LnSiO4] (Ln = Gd, Eu, Tb) 材料的热水合成情况.
- 调查结构和光物理性质,包括相变和发光.
- 探索它们作为光学温度计的潜在应用.
主要方法:
- 热水合成的热水合成
- 在各种温度下进行结构分析的X射线衍射 (XRD).
- 光发光光谱学 光发光光谱学
主要成果:
- 成功合成了Na[LnSiO4],具有无序的正方形结构.
- 观察到一个温度依赖的结构相变从Pnma到Imma对称度在100K以下.
- 具有独特的光物理特性,受结构转变和胺离子失调的影响.
- 开发了一种基于Na[(Gd0.8Eu0.1Tb0.1) SiO4的发光比度光学温度计,具有出色的冷灵敏度.
结论:
- Na[LnSiO4]系统表现出重要的结构阶段过渡,这对其特性至关重要.
- 开发的发光酸盐是用于冷应用的高效光学温度计.
- 这项工作为设计基于结构转换的先进光学温度计开辟了新的途径.
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