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Updated: Apr 17, 2026

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建模 TauD-J:一种高旋转的非海姆氧铁 (IV) 复合体,对 C-H 键具有很高的反应性

Achintesh N Biswas1, Mayank Puri, Katlyn K Meier

  • 1Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota , Minneapolis, Minnesota 55455, United States.

Journal of the American Chemical Society
|February 13, 2015
PubMed
概括

一个新的合成铁复合物[Fe (IV) (O) (TQA) (NCMe) ]2+有效氧化C-H和C=C键. 这种高度反应的五重旋转状态复合体是非海姆铁氧化酶酶的优秀模型.

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