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Updated: Apr 17, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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使用O2的Cp*Ir (III) (NHC) (Me) (Cl) 的氧功能化:识别了一种罕见的双金属Ir (IV) μ-oxo中间体

Matthew C Lehman1, Dale R Pahls2, Joseph M Meredith3

  • 1‡Department of Chemistry, North Carolina State University, 2620 Yarbrough Drive, Raleigh, North Carolina 27695-8204, United States.

Journal of the American Chemical Society
|February 22, 2015
PubMed
概括

这项研究详细介绍了利用空气作为氧化剂从复合物中形成甲醇的过程. 一个关键的中间体,一个带有Ir(IV) -O-Ir(IV) 核心的二金属复合物,被分离和表征.

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