同位素地质化学 同位素地质化学. 在O2的凝聚同位素中的生物特征
Laurence Y Yeung1, Jeanine L Ash2, Edward D Young3
1Department of Earth, Planetary, and Space Sciences, University of California, Los Angeles, CA 90095, USA. Department of Earth Science, Rice University, Houston, TX 77005, USA. lyeung@rice.edu jlash@ucla.edu.
概括
用于自然材料温度的聚合同位素分析受生物氧循环的影响. 这种生物过程在氧气聚集的同位素中产生独特的特征,而不是形成温度.
科学领域:
- 地质化学 地质化学
- 生物地质化学生物地质化学
- 同位素地球化学 同位素地球化学
背景情况:
- 分子中的聚合同位素被广泛用于确定自然材料的形成温度.
- 这些应用假设在物质形成过程中实现同位素交换平衡.
- "凝聚"同位素组成是指具有多个罕见同位素的分子.
研究的目的:
- 研究生物氧气循环对氧 (O2) 凝聚同位素组成的影响.
- 为了确定生物过程是否在O2凝聚的同位素中产生独特的特征,与形成温度不同.
- 评估O2凝聚同位素作为生物和地球化学循环的标记物的潜力.
主要方法:
- 为了模拟生物氧气循环,进行了封闭系统体实验.
- 在生物活性条件下测量了O2的凝聚同位素组成.
- 开发了一个模型来解释观察到的同位素特征.
主要成果:
- 生物氧气循环驱使O2的凝聚同位素组成远离同位素平衡.
- 与平衡条件相比,光合作用O2在 (18) O(18) O和 (17) O(18) O中被耗尽.
- 这种枯竭表明O2凝聚的同位素中具有独特的生物特征,而不是形成温度.
结论:
- 同位素平衡的假设并不总是适用于涉及O2.2的聚合同位素应用.
- 生物过程,特别是氧气循环,在O2.2上赋予了不同的同位素特征.
- 这些签名为追踪自然系统中的生物活动和地化学循环提供了新的途径.
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