一个新的核心/外NiAu/Au纳米粒子催化剂,具有Pt类活性,用于进化反应
Haifeng Lv1,2, Zheng Xi1, Zhengzheng Chen3
1†Department of Chemistry, Brown University, Providence, Rhode Island 02912, United States.
Journal of the American Chemical Society
|May 1, 2015
概括
研究人员开发了一种用于制造NiAu合金纳米粒子的通用方法. 这些纳米颗粒转化为核心/外结构,具有类活性,用于演变反应,提供卓越的耐用性.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 催化剂是一种催化剂.
背景情况:
- 开发高效且持久的演化反应 (HER) 催化剂对于可持续能源技术至关重要.
- 纳米粒子由于其高表面积和可调的组成,具有独特的催化性能.
研究的目的:
- 为金属合金纳米粒子 (NP) 开发一种通用合成方法,以增强演化反应 (HER) 的催化活性.
- 研究NiAu合金NP转化为核心/外NiAu/AuNP,并评估其催化性能.
主要方法:
- 在220°C的温度下与乙烯酸酸 (Ni(acac) 2) 和酸三水合物 (HAuCl4·3H2O) 在胺和油酸的存在下共同减少,形成NiAu合金NP.
- 在硫酸中循环的电化学潜力将NiAu NPs转化为核心/外NiAu/Au NPs.
- 第一个原则计算,以了解增强的催化活性的起源.
主要成果:
- 合成方法成功地产生了NiAu合金NP,在经过电化学处理后转化为核心/外NiAu/AuNP.
- 核心/外NiAu/Au NPs显著增强了HER的催化作用,实现了类似的活性和优越的耐用性.
- 第一原则计算表明,外上的低协调金矿场所有助于高催化活性.
结论:
- 建立了一种合成MAu/Au (M = Ni,Fe,Co) 核心/外纳米粒子的一般方法.
- 这些新型催化剂在水分和生成应用中,在效率和耐久性方面显示出超越的潜力.
- 这项研究为可持续能源生产提供了一类新的催化剂.
更多相关视频
06:32A Simple, Low-cost, and Robust System to Measure the Volume of Hydrogen Evolved by Chemical Reactions with Aqueous Solutions
Published on: August 17, 2016
20.5K
10:19Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation
Published on: July 18, 2017
12.7K
相关概念视频
Heterogeneous Catalysis
123
Heterogeneous catalysis involves a catalyst in a different phase from the reactants. It is a process where the catalyst and the reactants are in distinct phases, typically solid and gas or liquid.Most heterogeneous catalysts are metals, metal oxides, or acids. The list includes transition metals like iron (Fe), cobalt (Co), nickel (Ni), palladium (Pd), platinum (Pt), chromium (Cr), manganese (Mn), tungsten (W), silver (Ag), and copper (Cu). These metals possess partially vacant d orbitals that...
123
Catalysis
32.5K
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
32.5K
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
4.1K
Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
4.1K
Reduction of Alkenes: Catalytic Hydrogenation
15.0K
Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
15.0K
Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation
9.6K
Introduction
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
9.6K
