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Updated: Apr 13, 2026

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
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Published on: April 4, 2014

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通过金属循环介导的交叉合合成高度功能化的十素

Haruki Mizoguchi1, Glenn C Micalizio1

  • 1Department of Chemistry, Burke Laboratory, Dartmouth College, Hanover, New Hampshire 03755, United States.

Journal of the American Chemical Society
|May 2, 2015
PubMed
概括

这项研究引入了一种新的金属循环介导的无效反应,用于合成角替代的素,这是天然产品和制药中的关键结构. 反应可以控制中间稳定性,产生具有新立体中心的多环化合物.

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