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Updated: Apr 12, 2026

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
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四甲基乙等价物:为序列化循环添加剂的递归试剂.

Paul A Wender1, Matthew S Jeffreys1, Andrew G Raub1

  • 1Department of Chemistry, Department of Chemical and Systems Biology, Stanford University, Stanford, California 94305-5080, United States.

Journal of the American Chemical Society
|May 12, 2015
PubMed
概括

研究人员开发了新的试剂,使得序列 [4 + 2] 循环添加,有效地构建复杂的分子. 这一发现为合成药品和材料等有价值的化合物提供了一种节省步骤的方法.

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Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
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